Beyond the thermodynamic limit: finite-size corrections to state interconversion rates

Thermodynamics is traditionally constrained to the study of macroscopic systems whose energy fluctuations are negligible compared to their average energy. Here, we push beyond this thermodynamic limit by developing a mathematical framework to rigorously address the problem of thermodynamic transformations of finite-size systems. More formally, we analyse state interconversion under thermal operations and between arbitrary energy-incoherent states. We find precise relations between the optimal rate at which interconversion can take place and the desired infidelity of the final state when the system size is sufficiently large. These so-called second-order asymptotics provide a bridge between the extreme cases of single-shot thermodynamics and the asymptotic limit of infinitely large systems. We illustrate the utility of our results with several examples. We first show how thermodynamic cycles are affected by irreversibility due to finite-size effects. We then provide a precise expression for the gap between the distillable work and work of formation that opens away from the thermodynamic limit. Finally, we explain how the performance of a heat engine gets affected when one of the heat baths it operates between is finite. We find that while perfect work cannot generally be extracted at Carnot efficiency, there are conditions under which these finite-size effects vanish. In deriving our results we also clarify relations between different notions of approximate majorisation.Comment: 31 pages, 10 figures. Final version, to be published in Quantu

Tailoring surface codes for highly biased noise

The surface code, with a simple modification, exhibits ultra-high error correction thresholds when the noise is biased towards dephasing. Here, we identify features of the surface code responsible for these ultra-high thresholds. We provide strong evidence that the threshold error rate of the surface code tracks the hashing bound exactly for all biases, and show how to exploit these features to achieve significant improvement in logical failure rate. First, we consider the infinite bias limit, meaning pure dephasing. We prove that the error threshold of the modified surface code for pure dephasing noise is $50\%$, i.e., that all qubits are fully dephased, and this threshold can be achieved by a polynomial time decoding algorithm. We demonstrate that the sub-threshold behavior of the code depends critically on the precise shape and boundary conditions of the code. That is, for rectangular surface codes with standard rough/smooth open boundaries, it is controlled by the parameter $g=\gcd(j,k)$, where $j$ and $k$ are dimensions of the surface code lattice. We demonstrate a significant improvement in logical failure rate with pure dephasing for co-prime codes that have $g=1$, and closely-related rotated codes, which have a modified boundary. The effect is dramatic: the same logical failure rate achievable with a square surface code and $n$ physical qubits can be obtained with a co-prime or rotated surface code using only $O(\sqrt{n})$ physical qubits. Finally, we use approximate maximum likelihood decoding to demonstrate that this improvement persists for a general Pauli noise biased towards dephasing. In particular, comparing with a square surface code, we observe a significant improvement in logical failure rate against biased noise using a rotated surface code with approximately half the number of physical qubits.Comment: 18+4 pages, 24 figures; v2 includes additional coauthor (ASD) and new results on the performance of surface codes in the finite-bias regime, obtained with beveled surface codes and an improved tensor network decoder; v3 published versio

Quantum-embeddable stochastic matrices

The classical embeddability problem asks whether a given stochastic matrix $T$, describing transition probabilities of a $d$-level system, can arise from the underlying homogeneous continuous-time Markov process. Here, we investigate the quantum version of this problem, asking of the existence of a Markovian quantum channel generating state transitions described by a given $T$. More precisely, we aim at characterising the set of quantum-embeddable stochastic matrices that arise from memoryless continuous-time quantum evolution. To this end, we derive both upper and lower bounds on that set, providing new families of stochastic matrices that are quantum-embeddable but not classically-embeddable, as well as families of stochastic matrices that are not quantum-embeddable. As a result, we demonstrate that a larger set of transition matrices can be explained by memoryless models if the dynamics is allowed to be quantum, but we also identify a non-zero measure set of random processes that cannot be explained by either classical or quantum memoryless dynamics. Finally, we fully characterise extreme stochastic matrices (with entries given only by zeros and ones) that are quantum-embeddable.Comment: 14 pages, 3 figures, comments welcom

Tailoring three-dimensional topological codes for biased noise

Tailored topological stabilizer codes in two dimensions have been shown to exhibit high storage threshold error rates and improved subthreshold performance under biased Pauli noise. Three-dimensional (3D) topological codes can allow for several advantages including a transversal implementation of non-Clifford logical gates, single-shot decoding strategies, parallelized decoding in the case of fracton codes as well as construction of fractal lattice codes. Motivated by this, we tailor 3D topological codes for enhanced storage performance under biased Pauli noise. We present Clifford deformations of various 3D topological codes, such that they exhibit a threshold error rate of $50\%$ under infinitely biased Pauli noise. Our examples include the 3D surface code on the cubic lattice, the 3D surface code on a checkerboard lattice that lends itself to a subsystem code with a single-shot decoder, the 3D color code, as well as fracton models such as the X-cube model, the Sierpinski model and the Haah code. We use the belief propagation with ordered statistics decoder (BP-OSD) to study threshold error rates at finite bias. We also present a rotated layout for the 3D surface code, which uses roughly half the number of physical qubits for the same code distance under appropriate boundary conditions. Imposing coprime periodic dimensions on this rotated layout leads to logical operators of weight $O(n)$ at infinite bias and a corresponding $\exp[-O(n)]$ subthreshold scaling of the logical failure rate, where $n$ is the number of physical qubits in the code. Even though this scaling is unstable due to the existence of logical representations with $O(1)$ low-rate Pauli errors, the number of such representations scales only polynomially for the Clifford-deformed code, leading to an enhanced effective distance.Comment: 51 pages, 34 figure

Is the Welfare State Sustainable? Experimental Evidence on Citizens' Preferences for Redistribution

The sustainability of the welfare state ultimately depends on citizens' preferences for income redistribution. They are elicited through a Discrete Choice Experiment performed in 2008 in Switzerland. Attributes are redistribution as GDP share, its uses (the unemployed, old-age pensioners, people with ill health etc.), and nationality of beneficiary. Estimated marginal willingness to pay (WTP) is positive among those who deem benefits too low, and negative otherwise. However, even those who state that government should reduce income inequality exhibit a negative WTP on average. The major finding is that estimated average WTP is maximum at 21% of GDP, clearly below the current value of 25%. Thus, the present Swiss welfare state does not appear sustainable

Quantum dichotomies and coherent thermodynamics beyond first-order asymptotics

We address the problem of exact and approximate transformation of quantum dichotomies in the asymptotic regime, i.e., the existence of a quantum channel $\mathcal E$ mapping $\rho_1^{\otimes n}$ into $\rho_2^{\otimes R_nn}$ with an error $\epsilon_n$ (measured by trace distance) and $\sigma_1^{\otimes n}$ into $\sigma_2^{\otimes R_n n}$ exactly, for a large number $n$. We derive second-order asymptotic expressions for the optimal transformation rate $R_n$ in the small, moderate, and large deviation error regimes, as well as the zero-error regime, for an arbitrary pair $(\rho_1,\sigma_1)$ of initial states and a commuting pair $(\rho_2,\sigma_2)$ of final states. We also prove that for $\sigma_1$ and $\sigma_2$ given by thermal Gibbs states, the derived optimal transformation rates in the first three regimes can be attained by thermal operations. This allows us, for the first time, to study the second-order asymptotics of thermodynamic state interconversion with fully general initial states that may have coherence between different energy eigenspaces. Thus, we discuss the optimal performance of thermodynamic protocols with coherent inputs and describe three novel resonance phenomena allowing one to significantly reduce transformation errors induced by finite-size effects. What is more, our result on quantum dichotomies can also be used to obtain, up to second-order asymptotic terms, optimal conversion rates between pure bipartite entangled states under local operations and classical communication.Comment: 51 pages, 6 figures, comments welcom